|
|
all-trans-hexaprenyl_diphosphate + 4-Aminobenzoic_acid <=> 3-all_trans-hexaprenyl-4-aminobenzoate + diphosphate
|
2.5.1.39
4-hydroxybenzoate polyprenyltransferase
|
–
|
|
MetaCyc:
RXN-14291
|
|
|
|
3-all_trans-hexaprenyl-4-amino-5-hydroxybenzoate + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> 3,4-dihydroxy-5-all-trans-hexaprenylbenzoate + oxidized_ferredoxin + H2O + NH3
|
1.14.15.M57
|
–
|
|
MetaCyc:
RXN-20171
|
|
|
|
S-adenosyl-L-methionine + 3-demethylubiquinol-6 <=> H+ + ubiquinol-6 + S-adenosyl-L-homocysteine
|
2.1.1.64
3-demethylubiquinol 3-O-methyltransferase
|
–
|
|
BRENDA:
BS407326
MetaCyc:
RXN3O-102
|
|
|
|
S-adenosyl-L-methionine + 3,4-dihydroxy-5-all-trans-hexaprenylbenzoate <=> 3-methoxy-4-hydroxy-5-hexaprenylbenzoate + S-adenosyl-L-homocysteine + H+
|
2.1.1.114
polyprenyldihydroxybenzoate methyltransferase
|
–
|
|
BRENDA:
BS407322
KEGG:
R04711
MetaCyc:
RXN-20172
|
|
|
|
H+ + 3-methoxy-4-hydroxy-5-hexaprenylbenzoate <=> 2-Hexaprenyl-6-methoxyphenol + CO2
|
4.1.1
|
–
|
|
KEGG:
R06866
MetaCyc:
RXN3O-73
|
|
|
|
3-all_trans-hexaprenyl-4-aminobenzoate + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> 3-all_trans-hexaprenyl-4-amino-5-hydroxybenzoate + oxidized_ferredoxin + H2O
|
1.14.15.M57
|
–
|
|
MetaCyc:
RXN-14292
|
|
|
|
S-adenosyl-L-methionine + 2-methoxy-6-(all-trans-hexaprenyl)-1,4-benzoquinol <=> H+ + 2-all-trans-hexaprenyl-6-methoxy-3-methyl-1,4-benzoquinol + S-adenosyl-L-homocysteine
|
2.1.1.201
2-methoxy-6-polyprenyl-1,4-benzoquinol methylase
|
–
|
|
MetaCyc:
RXN3O-54
|
|
|
|
2-Hexaprenyl-6-methoxyphenol + O2 + NADPH + H+ <=> 2-methoxy-6-(all-trans-hexaprenyl)-1,4-benzoquinol + H2O + NADP+
|
1.14.13
|
–
|
|
MetaCyc:
RXN3O-12
|
|
|
|
2-all-trans-hexaprenyl-6-methoxy-3-methyl-1,4-benzoquinol + O2 + reduced_acceptor <=> 3-demethylubiquinol-6 + H2O + acceptor
|
1.14.99.60
3-demethoxyubiquinol 3-hydroxylase
|
–
|
|
MetaCyc:
RXN3O-75
|
|